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FPSC · CSS 2013

Chemistry

100 marks · 3 hours · 7 questions
This paper Chemistry · all yearsQ. 2a · What is engineering ceramics? Describe…Q. 4a · How CFT and MOT account…Q. 5 · System) Inner Orbital Complex: is…Q. 5a · Derive Schrodinger wave equation and…Q. 6a · How Debye-Huckel theory is applied…Q. 7a · How chorine is produced on…Q. 8a · Give the applications of chelates…With this paperPart-I MCQs1← 20122014 →
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Not yet checked 1 of 7 questions have not yet been compared with the official paper.

Part II

Q. 2a

What is engineering ceramics? Describe the raw materials used in making classic ceramic products.

(8)
Q. 4a

How CFT and MOT account for the fact that [CoF 6 ] 3- is paramagnetic but [Co(NH 3 ) 6 ] 3+ is diamagnetic?

(6)
Q. 5

System) Inner Orbital Complex: [Fe(CN)6]3−[Fe(CN)_6]^{3-} is low-spin ( d2sp3d^2sp^3 ) with only 1 unpaired electron: t2g5 eg0t_{2g}^{5} \, e_g^0 Outer Orbital Complex: [Fe(F)6]3−[Fe(F)_6]^{3-} is high-spin ( sp3d2sp^3d^2 ) with 5 unpaired electrons: t2g3 eg2t_{2g}^{3} \, e_g^2 3a Describe the oxyacids of chlorine.

Not yet checked
(6)
Q. 5a

Derive Schrodinger wave equation and calculate the energy of the particle in one dimensional box having length a.

(14)
Q. 6a

How Debye-Huckel theory is applied to determine activity and activity coefficients for strong electrolytes? Derive its mathematical form.

(12)
Q. 7a

How chorine is produced on industrial scale?

(8)
Q. 8a

Give the applications of chelates in biological and analytical systems.

(4)

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The 2013 CSS Chemistry paper set by the FPSC. Question wording only; questions marked “Not yet checked” have not been compared with the official paper yet.

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