(a)How would you synthesize each of the following molecule from an alkene of appropriate structure (structure of your choice). [8]
(b)Write the expected major product of the reaction of propyne with each of the following reagents. [6]
(c)Starting with benzene, design reasonable syntheses of each of the following compounds. [6]
(20)
Q. 4
(b)Draw the structures of the following molecules: [10]
(c)The structure(I) given below has significant dipole moment. Which end of the molecule would you expect to owe positive charge, and which tend to be negative. [2]
(20)
Q. 5
(a)Consider the reaction of bromocyclohexane with each of the four reagents below, and answer the questions below. Also write down the reaction mechanism in each case. [7]
(b)Evaluate each of the possible alcohol syntheses below as being good (the desired alcohol is major or only product), not so good (the desired alcohol is a minor product, or worthless). [5]
(20)
Q. 6
(c)Write the major product(s) of each of the following reactions. It is implied that aqueous work-up has taken place in all those cases that require it to obtain the organic product. [8]
(20)
Q. 7
Write a brief account on the following:
(a)Biological importance of starch [5]
(b)Classification of Amino acids [5]
(c)Primary structure of Proteins [5]
(d)Glycogenesis [5]
(20)
Q. 8
(a)Differentiate following using IR Spectroscopy? [4]
(b)What type of electronic transition are possible in the following compounds? [2]
(c)How will you distinguish the following compounds using UV/Visible spectrophotometer? [4]
(d)Give the chemical shift of the following compounds for each proton [5]
(e)The mass spectrum of compound shows following peaks: m/e= 120, relative intensity=20% (M⁺ peak), m/e= 105, relative intensity=80%, m/e= 77, relative intensity=96%, m/e= 43, relative intensity=35%. Assign the structure which would be expected. [5]
The 2016 CSS Chemistry paper set by the FPSC. Question wording only; questions marked “Not yet checked” have not been compared with the official paper yet.
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