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Part II Q. 2
(a) Write two equations of state for real gases and compare them high lighting their important features. [10] (b) Explain Heisenberg's uncertainty principle. [5] (c) Discuss Born's interpretation of wave function. [5] (10)
Q. 3
(a) Explain the Kohlrausch law. Why do the real solution should deviate from the law? [10] (b) Compare Langmuir's and Freundlich's adsorption isotherms. [10] (20)
Q. 4
(a) Explain the Arrhenius equation. Also high light its applications and limitations. [10] (b) Explain various acid-base theories. What are hard and soft acids and bases? [10] (20)
Q. 5
(a) Make a comparison of column chromatography and thin layer chromatography (TLC) by highlighting merits and demerits of the both. [10] (b) Explain Werner's theory of coordination complexes. Give examples from d-block transition metals. [10] (20)
Q. 6
(a) Give a comprehensive classification of various chromatographic techniques. Also mention potential application of each. [10] (b) What is Hydrogen bonding. Explain. [5] (c) Describe Hybidization in p-block elements. [5] (20)
Q. 7
(a) Explain crystal Field Theory (CFT) for d-block elements. [10] (b) Write an extensive essay on types of chemical bonding giving examples. [10] (20)
Q. 8
Write short notes on the following:
(i) Liquid junction potential [5] (ii) Potentiometry [5] (iii) Collision theory of Chemical reactions. [5] (iv) Transition state theory. [5] (20)