(a)Discuss the effect of temperature on rate of chemical reaction on the basis of Arrhenius equation. How can you determine activation energy and pre-exponential factor for a chemical reaction using Arrhenius equation? [10]
(b)Derive kinetic equation for 1st order reaction. [6]
(c)Prove that half life period for 1st order reaction is independent of initial concentration of reactant. [4]
(20)
Q. 6
(a)What is adsorption isotherm? Derive Langmuir adsorption isotherm for adsorption of a gas on solid surface. [10]
(b)What is enzyme catalysis? Discuss its kinetics. [6]
(c)What are surfactants? Give their properties. [4]
(20)
Q. 7
(a)What is electrophoresis? Give its principle and discuss its applications in biochemistry. [10]
(b)Give six chemical properties of nitrogen. [6]
(c)What is Common ions effect? Give its applications. [4]
(20)
Q. 8
(a)State John-Teller theorem. Explain it using suitable examples from coordination complexes. [10]
(b)Give postulates of Werner's theory of coordination complexes. [6]
(c)Briefly describe nuclear decay rate law for disintegration of radioactive elements. [4]
The 2017 CSS Chemistry paper set by the FPSC. Question wording only; questions marked “Not yet checked” have not been compared with the official paper yet.
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